Many have dreamed of being able to turn straw into gold like the fabled Rumpelstiltskin. While this may not be possible in the literal sense, scientists are using sunlight to turn straw into something more valuable.

With the aid of technology from the Canadian Light Source (CLS) at the University of Saskatchewan, Canadian researchers have made important advances to use the power of the sun to convert biomass like wheat straw into hydrogen fuel and value-added biochemicals. This method is more efficient, eco-friendly and lucrative.

Producing energy from biomass, or plant material, has been studied for more than four decades, said Dr. Jinguang Hu, assistant professor at the University of Calgary (UCalgary). The two most common processes are thermo-chemical and biological, but these are still carbon intensive and are not economically feasible.

Dr. Hu and Dr. Md Golam Kibria, an assistant professor at UCalgary, have been focusing their recent research on an alternative approach to commonly used petro-refinery.

Their novel and environmentally friendly approach called photobiorefinery uses solar energy to break down biomass, in this case wheat straw, to make green hydrogen and a high value biochemical. Canada First Research Excellence Fund (CFREF) has been supporting this research and their recent findings were published by the American Chemical Society.

One of the key aspects of an effective biomass photorefinery approach is pre-treatment of the wheat straw. Hu explained plant cell walls are made of complex and highly organized cellulose structures, a major building block of biomass.

Pre-treatment of the biomass destroys those structures and exposes more of the material to the sun-driven process. Kibria added the goal was to identify a pre-treatment that does not require non-renewable resources, thereby "saving a lot of carbon and cost."

Using the CLS's Hard X-ray Micro-analysis beamline, the researchers compared how raw wheat straw and straw pre-treated in a number of ways reacted in the photorefinery. Their findings showed a phosphoric acid pre-treatment resulted in the highest production of green hydrogen and lactic acid, which is typically used for bioplastics and in food, chemical, and medical industries.

"The CLS facility allowed us to see how stable the material was at the start, during and after photorefining of wheat straw. And, we could see that in real time, which is a big advantage," said Kibria.

Another critical factor was to find an inexpensive, readily available catalyst to drive the photorefinery. The study found the best results using a low-cost photocatalyst, made from carbon and nitrogen, that is designed for visible light driven cellulose photoreforming.

"Because all biomass has a similar chemical composition, what we've shown is that you can tailor the pre-treatment and the catalyst to valorize any renewable organic material," said Hu. This finding opens up opportunities for turning straw and other plant materials into value-added green hydrogen and biochemicals.

Kibria said the next steps in the research will be to "tune the catalyst to capture more of the visible light spectrum," and then to scale up the photorefinery with an eye to eventual commercialization.

"Because biomass captures carbon dioxide from the atmosphere, we can use this process to take care of the environment and produce green hydrogen and chemicals that are economically viable," he said.

Research Report: "Sunlight-Driven Biomass Photorefinery for Coproduction of Sustainable Hydrogen and Value-Added Biochemicals"

Related Links
Canadian Light Source
Bio Fuel Technology and Application News

Tweet

Thanks for being here; We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor $5 Billed Once credit card or paypal		SpaceDaily Monthly Supporter $5 Billed Monthly paypal only

Battered by virus and oil slump, biofuels fall out of favour
London (AFP) Nov 27, 2020
Hit by the coronavirus pandemic and a sharp drop in oil prices, biofuel demand has declined for the first time in two decades and may struggle to recover, according to experts. "The collapse of oil prices has had a very negative impact on biofuels," rendering them uncompetitive, Olivier Lemesle, director of studies at Xerfi, told AFP. The production of biofuels for transport in 2020 is expected to decline 11.6 percent on 2019 levels, the first fall in 20 years, according to the International En ... read more